Author: Deborah Birch (document modification date: 19th May 2003)

The Derivation of pKb

In deriving pKa we consider how much hydronium ion is formed when an acid is dissolved in water. So in deriving pKb we consider how much hydroxide ion a base will form in solution.

Kb equation

Like Ka though, we usually express Kb as a logarithm.

pKb = -log Kb

Therefore the scale is the same as the acid scale where the lower the pKb the stronger the base

How are these scales related?

How the two equations are related

The pKa scale however is more widely used and as the two scales are related one scale can suffice, therefore many textbooks and information sources will often only use pKa values.

The next page discusses factors which affect the basicity of a base.

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