9.7 Determining coordination number of f-block complexes

f-block coordination complexes' coordination numbers are difficult to determine in solution, but by looking at their crystal structures their coordination numbers can be deduced. Because the f-orbitals aren't available for bonding, and can be said to have a "core" like nature the geometry of the f-block metal complex is determined by the ligands datively bonded to it rather than it's electronic structure.
The ligand-ligand interactions reflect the geometry, rather than metal-ligand interactions, this gives rise to distorted complexes being much more common with f-block metals compared to d-block metal complexes.


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Author: Sally Robinson, date of modification: 20 March 2003